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- W1982946321 abstract "Abstract Asymmetric autocatalysis with amplification of enantiomeric excess is found in the enantioselective addition of diisopropylzinc to pyrimidine‐5‐carbaldehyde using pyrimidyl alkanol as an asymmetric autocatalyst. Asymmetric autocatalysis has been employed as a method for clarifying the origin of homochirality. Circularly polarized light, inorganic chiral crystals and statistical fluctuation of enantiomeric imbalance act as chiral initiators in asymmetric autocatalysis to afford highly enantioenriched products. We have investigated asymmetric autocatalysis using chiral crystals formed from achiral and racemic compounds as an origin of chirality. Absolute control of the crystal chirality of cytosine was achieved by the removal of crystal water. Enantioselective carbon‐carbon bond formation at the enantiotopic crystal face of aldehydes was established using diisopropylzinc vapor. In addition, asymmetric autocatalysis triggered by chiral compounds arising from H, C and O isotope substitution has been achieved." @default.
- W1982946321 created "2016-06-24" @default.
- W1982946321 creator A5057345662 @default.
- W1982946321 creator A5058976206 @default.
- W1982946321 date "2012-07-01" @default.
- W1982946321 modified "2023-10-04" @default.
- W1982946321 title "Asymmetric Autocatalysis Triggered by Chiral Crystals Formed from Achiral Compounds and Chiral Isotopomers" @default.
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- W1982946321 doi "https://doi.org/10.1002/ijch.201100155" @default.
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