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- W1982981910 abstract "Cyclic voltammetry, potential-dependent chronoamperometry and controlled potential electrolysis have been used to investigate the redox reactions which the nickel-triphenylphosphine system undergoes in acetonitrile solution in the presence of the activated olefin acrylonitrile. For the reduction of Ni(II) electrochemically generated in this medium, a mechanism is proposed which is consistent with the data. This species undergoes an irreversible two-electron reduction giving the corresponding Ni(0) complex which reacts quickly with the olefin. In this last homogeneous redox reaction an unusual and not previously reported olefin-Ni(I) derivative is obtained. The geometric configuration of such an organometallic compound has been then inferred on the basis of near-infrared and ESR spectra." @default.
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- W1982981910 date "1983-12-01" @default.
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- W1982981910 title "An electroanalytical investigation on the nickel-triphenylphosphine system in the presence of acrylonitrile" @default.
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- W1982981910 doi "https://doi.org/10.1016/s0022-0728(83)80318-0" @default.
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