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- W1983004593 abstract "Reaction of (R3P)AuCl with some 1-unsubstituted 2-pyridones and alkali in homogeneous or heterogeneous medium has given (R3P)AuQ compounds (QH is 2-pyridone, 3-nitro-, 5-chloro-, or 6-methyl-pyridone; R is t-Bu, cyclo-hexyl, phenyl, or 1-naphthyl). Combined infrared and NMR evidence indicates that the compounds are derived from the 2-pyridone tautomer, the metal being in the 1-position. An X-ray crystal structure determination carried out on Ph3PAu(6-methylpyridonato-N)· H2O· 0.5C6H6, the first structural analysis on a derivative in which the Q ligand is monodentate, reveals that the pyridonato-N ligand is derived from the keto-tautomer, the CO distance being 1.23(2) Å, and that the coordination around the gold atom is approximately linear (PAuN 173.4(3)°). with AuN 2.077(9), AuP 2.236(3) Å and no metal-metal interaction." @default.
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- W1983004593 date "1985-11-01" @default.
- W1983004593 modified "2023-10-17" @default.
- W1983004593 title "(Tertiary phosphine)gold(I) derivatives of 2-pyridones" @default.
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- W1983004593 doi "https://doi.org/10.1016/0022-328x(85)80357-0" @default.
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