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- W1983092014 abstract "Abstract Among the ir spectral changes occurring in aSi:H exposed to ambient atmosphere is the change in magnitude of the SiHn stretching region. While this change is correlated with the extent of oxidation, no frequency shifts occur until the material is heavily oxidized. Inductive effects, previously used to correlate all known SiHn stretching vibrations in monomers and in aSi:H, are used to predict the behavior of these vibrations on contamination with adjacent carbon- and oxygen-containing species. The predicted peaks all fall at the SiH, SiH2 and SiH3 stretching frequencies except at high oxygen contents; there, the experimental red shifts are predicted. The relative lack of influence of carbon-containing species on these vibrations is shown to be due to its inductive effect, almost identical in sign and magnitude to that of the pristine silicon structure." @default.
- W1983092014 created "2016-06-24" @default.
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- W1983092014 date "1986-07-01" @default.
- W1983092014 modified "2023-09-27" @default.
- W1983092014 title "Predictions of SiHn stretching vibrations on atmospheric contamination of hydrogenated amorphous silicon" @default.
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- W1983092014 doi "https://doi.org/10.1016/0165-1633(86)90076-6" @default.
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