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• W1983105740 abstract "Thermal decomposition of formaldehyde diluted with Ar was studied behind reflected shock waves in the temperature range of 1200–2000 K at total pressures between 1.3 and 3.0 atm. The study was carried out for compositions from the concentrated mixture, 4% CH2O, to the highly dilute mixture, 0.01% CH2O by using time-resolve IR-laser absorption and IR-emission, and a single-pulse technique. From a computer-simulation study, the mechanism and the rate-constant expressions that could explain all of our data and previously reported ARAS data were discussed. This data obtained over a wide concentration range from 50 ppm CH2O to 4% CH2O were satisfactorily modeled by a five-reaction mechanism. © 1993 John Wiley & Sons, Inc." @default.
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• W1983105740 date "1993-04-01" @default.
• W1983105740 modified "2023-09-29" @default.
• W1983105740 title "High temperature pyrolysis of formaldehyde in shock waves" @default.
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• W1983105740 doi "https://doi.org/10.1002/kin.550250409" @default.
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