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- W1983156297 abstract "Diethylaminosulfur triflouride (DAST) reacts with epoxides (oxiranes) to form geminal diflourides, vicinal diflourides, and bis(2-fluoroalkyl) ethers. Thus cyclopentene oxide gave cis-1,2-difluorocyclopentane and bis(2-fluorocyclopentyl) ether; cyclohexene oxide gave cis-1,1-difluorocyclohexane and bis(2-fluorocylohexyl) ether; styrene oxide gave 1,1-difluoroethylbenzene and 1,2-difluoroethylbenzene; and cis- and trans-stilbene oxides gave mixtures of meso- and racemic 1,2-difluoro-1,2-diphenylethanes together with 1,1-difluoro-2,2-diphenylethane resulting from a rearrangement. Cyclooctene oxide and cyclohexene sulfide do not react appreciably under the same conditions." @default.
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- W1983156297 date "1987-09-01" @default.
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- W1983156297 title "Reaction of epoxides with diethylaminosulfur triflouride" @default.
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- W1983156297 doi "https://doi.org/10.1016/s0022-1139(00)81979-x" @default.
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