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- W1983194966 abstract "Synthesis of stereoisomeric 3-deoxy-hexoses 24–27 and 3,6-dideoxy-hexoses 28–31 is reported. Butyl (E)-2,6-dihydroxy-hex-4-enoate (2) was used as the starting material for the synthesis of 3-deoxy-hexoses. For the synthesis of 3,6-dideoxy-hexoses, butyl (E)-2-acetoxy-hex-4-enoate (7) was employed. The synthesis involved the following successive steps: cis or trans hydroxylation of the double bond in 2 or 7, lactonisation of the resulting aldonic acid esters followed by acetylation and chromatographical separation of γ-lactones, reduction of lactones 16–23 to lactols with disiamylborane, and acetylation of lactols to free sugars. All compounds were obtained as pure diastereomers in racemic form." @default.
- W1983194966 created "2016-06-24" @default.
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- W1983194966 date "1980-01-01" @default.
- W1983194966 modified "2023-10-17" @default.
- W1983194966 title "Total synthesis of 3-deoxy and 3,6-dideoxy-dl-hexoses" @default.
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- W1983194966 doi "https://doi.org/10.1016/0040-4020(80)80132-3" @default.
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