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- W1983199097 abstract "Abstract The tripeptide complex Pd(gly- l -his- l -lys)Cl (Pd(GHK)Cl. 1 ) has been studied by a variety of NMR techniques ( 1 H, 1 H E.COSY, 1 H NOESY, 1 H, 13 C HMQC), by ESI-MS, as well as simulated annealing and molecular dynamics methods. Reactions of 1 with isolated 5′-deoxynucleotides of guanine, cytidine, adenine and thymine, alone and in competition, have been carried out in water and followed by 1 H NMR spectroscopy. They reveal preferential binding of Pd(GHK) + to guanine N7 in weakly to moderately acidic solution and slow rotation of the Pd tripeptide entity about the metal-N7 bond below 276 K. The self-complementary tetranucleotide 5′-d(GTAC) reacts with 1 in D 2 O, pD 3.5, at guanine N7." @default.
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- W1983199097 date "1998-05-01" @default.
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- W1983199097 title "Pd(gly-l-his-l-lys)Cl: Solution structure and ternary complex formation with mono- and tetranucleotides" @default.
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- W1983199097 doi "https://doi.org/10.1016/s0020-1693(97)06011-8" @default.
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