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- W1983206362 abstract "The bis(pentamethylcyclopentadienyl)thorium(IV) complex Cp2*ThI2 (Cp* = η5-C5Me5) was readily synthesized from the dibromo derivative Cp2*ThBr2 using a slight excess of trimethylsilyl iodide (Me3SiI). The thorium complex Cp2*ThI2 exhibits a ‘bent metallocene’ structure, as determined by single-crystal X-ray diffraction (monoclinic, space group P21/n; a = 8.572(2), b = 16.718(3), c = 15.881(2) Å; β = 98.16(2)o; V = 2252.8(8) Å3; Z = 4)." @default.
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- W1983206362 date "1998-06-01" @default.
- W1983206362 modified "2023-10-16" @default.
- W1983206362 title "Trimethylsilyl iodide as a halide exchange reagent in inorganic chemistry: synthesis and structure of Cp2*ThI2 (Cp* = η5-C5Me5)" @default.
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- W1983206362 doi "https://doi.org/10.1016/s0020-1693(97)06051-9" @default.
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