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• W1983207864 endingPage "1852" @default.
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• W1983207864 abstract "In the present work, tellurite 20Li2O–80TeO2 glasses were prepared with identical nominal composition under different glass-forming histories to produce a stressed and stress-free samples. X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) techniques were used to study the effects of the glass-forming histories on the thermal and structural properties of these glasses. The γ-TeO2 (metastable), α-TeO2 and α-Li2Te2O5 phases were identified during the controlled devitrification in these glasses. The mestastable character of the γ-TeO2 phase was clearly observed in the glass under stress but this effect is not so clear in the stress-free glass. The γ-TeO2 and α-TeO2 phases crystallizes during the initial stages of crystallization in both studied glasses while the α-Li2Te2O5 phase crystallize in the final stages of the crystallization. The activation energies and Avrami exponent were calculated for both studied glasses with different particle size leading to E3 > E2 > E1 for stressed glass and E3 > E2 ≈ E1 for stress-free glass, where E1, E2 and E3 were associated to the γ-TeO2, α-TeO2 and α-Li2Te2O5 phases, respectively. The observed distinct n¯1<n¯2<n¯3 in both glasses is an indicative that nucleation and growth takes place by more than one mechanism in the early stages of the crystallization." @default.
• W1983207864 created "2016-06-24" @default.
• W1983207864 creator A5060434636 @default.
• W1983207864 creator A5090207774 @default.
• W1983207864 date "2011-10-01" @default.
• W1983207864 modified "2023-09-30" @default.
• W1983207864 title "Effects of glass-forming histories on the crystallization kinetic of the 20Li2O–80TeO2 glass" @default.
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• W1983207864 doi "https://doi.org/10.1016/j.optmat.2011.02.044" @default.
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