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- W1983223870 abstract "Suspension copolymerizations of α-chloroacrylonitrile and divinylbenzene have been carried out both with and without diluents. The polymers are macroporous except for those without diluent and of higher crosslinker content. At a fixed divinylbenzene content, the macroporosity increases with diluent content and is always higher with nonsolvating diluent. The gross morphologic features of the polymers depend on the crosslink density and on both the nature and amount of the diluent; scanning electron micrographs of typical examples are shown. Semicarbons are readily produced by dehydrochlorination. On full carbonization at 900°C, microporous carbons are produced which have some residual nitrogen-containing groups able to act as specific sites for anionic adsorbates. Homopoly α-chloroacrylonitrile fuses on heating to 900°C unless it has been previously dehydrochlorinated by treatment with base. All crosslinked polymers give carbons which are pseudomorphs of the original specimens." @default.
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- W1983223870 date "1975-12-01" @default.
- W1983223870 modified "2023-09-24" @default.
- W1983223870 title "Porous polymer carbons. V. Macroporous carbons from crosslinked α-chloroacrylonitrile polymers" @default.
- W1983223870 doi "https://doi.org/10.1002/app.1975.070191217" @default.
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