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• W1983232169 abstract "The competitive kinetics of additions of allyl to benzaldehyde-h and -d from allyltributyl tin, from diisopropyltartrylallyl boronate, and from allyl bromide and zinc dust in aqueous tetrahydrofuran have inverse secondary deuterium kinetic isotope effects, SDKIEs. These inverse SDKIEs are in contrast to the normal SDKIEs that were obtained with allyl lithium and allyl Grignard, suggesting rate-determining single-electron transfer in these cases. By various MO calculations the transition state for addition of allyl boronate occurs with substantial B-O bond formation and little C-C bond formation. The magnitudes of the SDKIEs with the other two allylating reagents, when compared with reasonable equilibrium isotope effects for the addition, suggest transition states with substantial C-C bond formation." @default.
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• W1983232169 date "2002-05-18" @default.
• W1983232169 modified "2023-10-17" @default.
• W1983232169 title "Secondary Deuterium Kinetic Isotope Effects in Irreversible Additions of Allyl Reagents to Benzaldehyde" @default.
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• W1983232169 doi "https://doi.org/10.1021/jo0164002" @default.
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