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- W1983245997 abstract "Measurements are made on optical absorption from 350 to 2500 nm at 77 °K of ZnS crystals irradiated by fast neutrons at room temperature and of those fired in a zinc or sulfur vapour at 1100 °C. It has been found that neutron irradiation produces photoinsensitive 2.7 and 1.75 eV bands in addition to the 3.5, 3.2, 2.9, and 2.3 eV bands reported previously, and that the firing in zinc vapour produces new photosensitive 3.2, 2.7, and 1.75 eV bands. All of the six bands produced by neutron irradiation are also produced by the firing in zinc vapour. However these bands can not be produced by the firing in sulfur vapour, which produces four bands different from those induced by the zinc firing. It is proposed that the 3.5, 3.2, 2.7, and 1.75 eV bands are related with sulfur vacancies and that the 2.7 and 1.75 eV bands are due to hole transitions. Optische Absorptionsmessungen zwischen 350 und 2500 nm wurden bei 77 °K an bei Zimmertemperatur mit schnellen Neutronen bestrahlten und im Zink- oder Schwefeldampf bei 1100 °C getemperten ZnS-Kristallen durchgeführt. Es wird gefunden, daß die Neutro-nenbestrahlung lichtunempfindliche Banden bei 2,7 und 1,75 eV, außer den veröffentlichten 3,5-, 3,2-, 2,9- und 2,3 eV-Banden, hervorruft und daß die im Zinkdampf getemperten Kristalle neue lichtempfindliche Banden bei 3,2, 2,7 und 1,75 eV hervorrufen. Alle mit Neutronenbestrahlung erzeugten, oben erwähnten sechs Banden werden auch durch die Zink-dampftemperung hervorgerufen, aber nicht durch die Schwefeldampftemperung, die von diesen Banden verschiedene, vier andere Banden erzeugt. Es wird vermutet, daß diese 3,5-, 3,2-, 2,7- und 1,75 eV-Banden mit Schwefellücken zusammenhängen und daß die 2,7- und 1,75 eV-Banden von Löcherübergängen herrühren." @default.
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- W1983245997 date "1975-03-16" @default.
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- W1983245997 title "Optical absorption and lattice defects induced by neutron irradiation and heat treatment in ZnS crystals" @default.
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- W1983245997 doi "https://doi.org/10.1002/pssa.2210280144" @default.
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