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• W1983251204 endingPage "6145" @default.
• W1983251204 startingPage "6130" @default.
• W1983251204 abstract "Abstract The preparation, X‐ray crystallography and magnetic investigation of the compounds PPh 4 [Cr(bipy)(CN) 4 ] ⋅ 2 CH 3 CN ⋅ H 2 O ( 1 ) (mononuclear), [{Cr(bipy)(CN) 4 } 2 Mn(H 2 O) 4 ] ⋅ 4 H 2 O ( 2 ) (trinuclear), [{Cr(bipy)(CN) 4 } 2 Mn(H 2 O) 2 ] ( 3 ) (chain) and [{Cr(bipy)(CN) 4 } 2 Mn(H 2 O)] ⋅ H 2 O ⋅ CH 3 CN ( 4 ) (double chain) [bipy=2,2′‐bipyridine; PPh 4 + =tetraphenylphosphonium] are described herein. The [Cr(bipy)(CN) 4 ] − unit act either as a monodentate ( 2 ) or bis‐monodentate ( 3 ) ligand toward the manganese atom through one ( 2 ) or two ( 3 ) of its four cyanide groups. The manganese atom is six‐coordinate with two ( 2 ) or four ( 3 ) cyanide nitrogens and four ( 2 ) or two ( 3 ) water molecules building a distorted octahedral environment. In 4 , two chains of 3 are pillared through interchain Mn‐N‐C‐Cr links which replace one of the two trans ‐coordinated water molecules at the manganese atom to afford a double chain structure where bis‐ and tris‐monodenate coordination modes of [Cr(bipy)(CN) 4 ] − coexist. The magnetic properties of 1 – 4 were investigated in the temperature range 1.9–300 K. A Curie law behaviour for a magnetically isolated spin quartet is observed for 1 . A significant antiferromagnetic interaction between Cr III and Mn II through the single cyanide bridge [ J =−6.2 cm −1 , the Hamiltonian being defined as Ĥ =− J ( Ŝ Cr(1) ⋅ Ŝ Mn + Ŝ Cr(2) ⋅ Ŝ Mn )] occurs in 2 leading to a low‐lying spin doublet which is fully populated at T <5 K. A metamagnetic behaviour is observed for 3 and 4 [the values of the critical field H c being ca. 3000 ( 3 ) and 1500 Oe ( 4 )] which is associated to the occurrence of weak interchain antiferromagnetic interactions between ferrimagnetic ${{rm Cr}{{{rm III}hfill atop 2hfill}}}$ Mn II chains. The analysis of the exchange pathways in 2 – 4 through DFT type calculations together with the magnetic bevaviour simulation using the quantum Monte Carlo methodology provided a good understanding of their magnetic properties." @default.
• W1983251204 created "2016-06-24" @default.
• W1983251204 creator A5018760070 @default.
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• W1983251204 creator A5088790682 @default.
• W1983251204 date "2004-11-18" @default.
• W1983251204 modified "2023-10-17" @default.
• W1983251204 title "Nuclearity Controlled Cyanide-Bridged Bimetallic Cr^III-Mn^IICompounds: Synthesis, Crystal Structures, Magnetic Properties and Theoretical Calculations" @default.
• W1983251204 cites W123872719 @default.
• W1983251204 cites W1577234663 @default.
• W1983251204 cites W1906158645 @default.
• W1983251204 cites W1963695948 @default.
• W1983251204 cites W1964664772 @default.
• W1983251204 cites W1964798075 @default.
• W1983251204 cites W1964824663 @default.
• W1983251204 cites W1965639287 @default.
• W1983251204 cites W1968470404 @default.
• W1983251204 cites W1972493784 @default.
• W1983251204 cites W1978279738 @default.
• W1983251204 cites W1983807847 @default.
• W1983251204 cites W1992069141 @default.
• W1983251204 cites W1993398919 @default.
• W1983251204 cites W1996547092 @default.
• W1983251204 cites W1999304304 @default.
• W1983251204 cites W2006038032 @default.
• W1983251204 cites W2008691240 @default.
• W1983251204 cites W2011254772 @default.
• W1983251204 cites W2012777271 @default.
• W1983251204 cites W2015632199 @default.
• W1983251204 cites W2018449516 @default.
• W1983251204 cites W2019657206 @default.
• W1983251204 cites W2023219625 @default.
• W1983251204 cites W2023271753 @default.
• W1983251204 cites W2024115887 @default.
• W1983251204 cites W2024214423 @default.
• W1983251204 cites W2025314884 @default.
• W1983251204 cites W2025492100 @default.
• W1983251204 cites W2026595283 @default.
• W1983251204 cites W2026753780 @default.
• W1983251204 cites W2027643101 @default.
• W1983251204 cites W2030446652 @default.
• W1983251204 cites W2032427861 @default.
• W1983251204 cites W2033224394 @default.
• W1983251204 cites W2038767330 @default.
• W1983251204 cites W2041934805 @default.
• W1983251204 cites W2044814053 @default.
• W1983251204 cites W2045027581 @default.
• W1983251204 cites W2046471185 @default.
• W1983251204 cites W2047013997 @default.
• W1983251204 cites W2047602127 @default.
• W1983251204 cites W2048262633 @default.
• W1983251204 cites W2052034051 @default.
• W1983251204 cites W2052454557 @default.
• W1983251204 cites W2053072074 @default.
• W1983251204 cites W2058210956 @default.
• W1983251204 cites W2059290636 @default.
• W1983251204 cites W2063334178 @default.
• W1983251204 cites W2065570758 @default.
• W1983251204 cites W2070796674 @default.
• W1983251204 cites W2071095959 @default.
• W1983251204 cites W2074286939 @default.
• W1983251204 cites W2077039404 @default.
• W1983251204 cites W2078146328 @default.
• W1983251204 cites W2081626220 @default.
• W1983251204 cites W2081729676 @default.
• W1983251204 cites W2082121329 @default.
• W1983251204 cites W2085791912 @default.
• W1983251204 cites W2086957099 @default.
• W1983251204 cites W2087896221 @default.
• W1983251204 cites W2089796724 @default.
• W1983251204 cites W2091686067 @default.
• W1983251204 cites W2095367268 @default.
• W1983251204 cites W2099330403 @default.
• W1983251204 cites W2101748147 @default.
• W1983251204 cites W2104296955 @default.
• W1983251204 cites W2104350867 @default.
• W1983251204 cites W2104383328 @default.
• W1983251204 cites W2123928103 @default.
• W1983251204 cites W2125414929 @default.
• W1983251204 cites W2135374860 @default.
• W1983251204 cites W2143981217 @default.
• W1983251204 cites W2146281029 @default.
• W1983251204 cites W2149997038 @default.
• W1983251204 cites W2153781180 @default.
• W1983251204 cites W2157130023 @default.
• W1983251204 cites W2160240507 @default.
• W1983251204 cites W2161926822 @default.
• W1983251204 cites W2162367935 @default.
• W1983251204 cites W2167528955 @default.
• W1983251204 cites W2171768658 @default.
• W1983251204 cites W2325116266 @default.
• W1983251204 cites W2949369679 @default.

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