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• W1983252607 endingPage "581" @default.
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• W1983252607 abstract "Superconductive YBCO thin films have been prepared by trifluoroacetate (TFA) metalorganic deposition (MOD) method. Non-stoichiometric precursor solutions with cation ratios of Y:Ba:Cu = 1 + x:2:3 (x = 0, 0.05, 0.1, 0.15 and 0.2) have been prepared by dissolving high purity Y2O3, BaCO3 and CuO powders into trifluoroacetate. Coated film was calcined at lower temperature in a moisture-containing oxygen atmosphere. Superconducting YBCO films have been obtained by conducting a conversion heat treatment at higher temperature in a moisture-containing Ar (1000 ppm oxygen) atmosphere. Critical current density (Jc) of YBCO film was increased with the amount of excess yttrium in YBCO film and revealed maximum Jc for x = 0.15 and decreased again for x = 0.2. Four times higher Jc was obtained for the film with x = 0.15 compared to that of the film prepared from stoichiometric solution of Y:Ba:Cu = 1:2:3. It is considered that the densification of microstructure and absence of a-axis grains attributed to the enhancement of Jc in the film made of non-stoichiometric solution." @default.
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• W1983252607 date "2006-10-01" @default.
• W1983252607 modified "2023-10-06" @default.
• W1983252607 title "Effect of precursor composition on Jc enhancement of YBCO film prepared by TFA-MOD method" @default.
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• W1983252607 doi "https://doi.org/10.1016/j.physc.2006.04.084" @default.
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