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• W1983284349 startingPage "131" @default.
• W1983284349 abstract "The oxygen- and sulfur-induced aggregation of cobalt in mixed Co-oxygen and Co-sulfur overlayers on Mo(110) have been studied using X-ray photoelectron and temperature-programmed desorption spectroscopies and low-energy electron diffraction. X-ray photoelectron data indicate that deposition of oxygen on 1 monolayer of Co results in the formation of Co oxide, which begins to decompose above 400 K. Only minor amounts of Co oxide are formed when 1 ML of Co is deposited on an oxygen overlayer. After annealing to 965 K for 60 s, the attenuation of the Co X-ray photoelectron signal and the temperature-programmed desorption data provide evidence for migration of oxygen to Mo and formation of three-dimensional Co clusters. Sulfur in mixed CoS overlayers also induces Co island formation as sulfur bonds to Mo, although to a lesser extent than oxygen. The Co aggregation is explained in terms of the thermodynamic preference for oxygen and sulfur to bond to Mo over Co. These studies provide a means of constructing phases that can be used to investigate structural effects in surface reactions." @default.
• W1983284349 created "2016-06-24" @default.
• W1983284349 creator A5023234085 @default.
• W1983284349 creator A5073066134 @default.
• W1983284349 date "1997-01-01" @default.
• W1983284349 modified "2023-10-12" @default.
• W1983284349 title "Adsorbate-induced structural changes of metal thin films: cobalt-oxygen and cobalt-sulfur overlayers on Mo(110)" @default.
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• W1983284349 doi "https://doi.org/10.1016/s0039-6028(96)00952-1" @default.
• W1983284349 hasPublicationYear "1997" @default.
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