Matches in SemOpenAlex for { <https://semopenalex.org/work/W1983286988> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W1983286988 endingPage "1722" @default.
- W1983286988 startingPage "1715" @default.
- W1983286988 abstract "The polymerization of ethynyltrimethylsilane with {Pd[C C-Si(CH3)3)]2(PPh3)2} in different complex: monomer ratios has been investigated. Polymers containing Pd(II) have been isolated and characterized by means of X.p.s. and FT i.r. measurements. The insoluble polymers obtained contain Pd sites that are σ-bonded to the π-conjugated growth chain and coordinated to the C C bonds of adjacent chains in a crosslinked structure. The soluble polymers isolated have a linear structure where Pd(II) coordinates through σ-bonds to the polymeric chains and to OPPh3 ligands. If NHEt2 is used as the polymerization solvent, substitution of Si(CH3)3 by N(C2H5)2 groups occurs, catalysed by the Pd complex. Comparison of the X.p.s. and g.p.c. measurements and elemental analyses give an estimation of the number of monomer repeat units for every Pd atom." @default.
- W1983286988 created "2016-06-24" @default.
- W1983286988 creator A5016026072 @default.
- W1983286988 creator A5054363905 @default.
- W1983286988 creator A5073588593 @default.
- W1983286988 creator A5078448269 @default.
- W1983286988 date "1996-04-01" @default.
- W1983286988 modified "2023-10-14" @default.
- W1983286988 title "Synthesis and characterization of poly(ethynyltrimethylsilane) containing Pd(II) coordination sites" @default.
- W1983286988 cites W1486235811 @default.
- W1983286988 cites W1967027584 @default.
- W1983286988 cites W1985626425 @default.
- W1983286988 cites W1988812967 @default.
- W1983286988 cites W1992214743 @default.
- W1983286988 cites W1995691657 @default.
- W1983286988 cites W2002888536 @default.
- W1983286988 cites W2009048409 @default.
- W1983286988 cites W2011601972 @default.
- W1983286988 cites W2024844451 @default.
- W1983286988 cites W2026208893 @default.
- W1983286988 cites W2030670560 @default.
- W1983286988 cites W2037277781 @default.
- W1983286988 cites W2042606689 @default.
- W1983286988 cites W2065362597 @default.
- W1983286988 cites W2077534030 @default.
- W1983286988 cites W2081301835 @default.
- W1983286988 cites W2090916671 @default.
- W1983286988 cites W2094744701 @default.
- W1983286988 cites W2161976226 @default.
- W1983286988 cites W2163214667 @default.
- W1983286988 doi "https://doi.org/10.1016/0032-3861(96)83724-4" @default.
- W1983286988 hasPublicationYear "1996" @default.
- W1983286988 type Work @default.
- W1983286988 sameAs 1983286988 @default.
- W1983286988 citedByCount "28" @default.
- W1983286988 countsByYear W19832869882012 @default.
- W1983286988 countsByYear W19832869882013 @default.
- W1983286988 countsByYear W19832869882014 @default.
- W1983286988 countsByYear W19832869882018 @default.
- W1983286988 crossrefType "journal-article" @default.
- W1983286988 hasAuthorship W1983286988A5016026072 @default.
- W1983286988 hasAuthorship W1983286988A5054363905 @default.
- W1983286988 hasAuthorship W1983286988A5073588593 @default.
- W1983286988 hasAuthorship W1983286988A5078448269 @default.
- W1983286988 hasConcept C112613896 @default.
- W1983286988 hasConcept C149635348 @default.
- W1983286988 hasConcept C161790260 @default.
- W1983286988 hasConcept C166940927 @default.
- W1983286988 hasConcept C178790620 @default.
- W1983286988 hasConcept C185592680 @default.
- W1983286988 hasConcept C188027245 @default.
- W1983286988 hasConcept C192562407 @default.
- W1983286988 hasConcept C2780471494 @default.
- W1983286988 hasConcept C41008148 @default.
- W1983286988 hasConcept C44228677 @default.
- W1983286988 hasConcept C502130503 @default.
- W1983286988 hasConcept C521977710 @default.
- W1983286988 hasConcept C58312451 @default.
- W1983286988 hasConcept C8010536 @default.
- W1983286988 hasConceptScore W1983286988C112613896 @default.
- W1983286988 hasConceptScore W1983286988C149635348 @default.
- W1983286988 hasConceptScore W1983286988C161790260 @default.
- W1983286988 hasConceptScore W1983286988C166940927 @default.
- W1983286988 hasConceptScore W1983286988C178790620 @default.
- W1983286988 hasConceptScore W1983286988C185592680 @default.
- W1983286988 hasConceptScore W1983286988C188027245 @default.
- W1983286988 hasConceptScore W1983286988C192562407 @default.
- W1983286988 hasConceptScore W1983286988C2780471494 @default.
- W1983286988 hasConceptScore W1983286988C41008148 @default.
- W1983286988 hasConceptScore W1983286988C44228677 @default.
- W1983286988 hasConceptScore W1983286988C502130503 @default.
- W1983286988 hasConceptScore W1983286988C521977710 @default.
- W1983286988 hasConceptScore W1983286988C58312451 @default.
- W1983286988 hasConceptScore W1983286988C8010536 @default.
- W1983286988 hasIssue "9" @default.
- W1983286988 hasLocation W19832869881 @default.
- W1983286988 hasOpenAccess W1983286988 @default.
- W1983286988 hasPrimaryLocation W19832869881 @default.
- W1983286988 hasRelatedWork W1980023817 @default.
- W1983286988 hasRelatedWork W2001706465 @default.
- W1983286988 hasRelatedWork W2002585280 @default.
- W1983286988 hasRelatedWork W2020386750 @default.
- W1983286988 hasRelatedWork W2077709699 @default.
- W1983286988 hasRelatedWork W2083916868 @default.
- W1983286988 hasRelatedWork W2103909536 @default.
- W1983286988 hasRelatedWork W2171219375 @default.
- W1983286988 hasRelatedWork W2381737861 @default.
- W1983286988 hasRelatedWork W99637172 @default.
- W1983286988 hasVolume "37" @default.
- W1983286988 isParatext "false" @default.
- W1983286988 isRetracted "false" @default.
- W1983286988 magId "1983286988" @default.
- W1983286988 workType "article" @default.