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- W1983307098 abstract "The dependence of the ns-density at the nucleus, | ψ ns (0) | 2, on atomic number and charge is examined for the elements helium to radon. The validity of the widely used assumption of a constant valence s-density at the nucleus, as well as the statement that metal-phosphorus NMR. coupling constants, 1J (M,P), are strongly influenced by contraction of the phosphorus 3 s orbital is critisized. A possible explanation by rehybridisation within an MO-framework is offered instead." @default.
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- W1983307098 date "1980-10-29" @default.
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- W1983307098 title "An Investigation of Charge Effects on NMR. Coupling Constants. The Charge Induced Variation of s-Densities at the Nucleus" @default.
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- W1983307098 doi "https://doi.org/10.1002/hlca.19800630733" @default.
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