FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1983340908> ?p ?o ?g. }

• W1983340908 endingPage "51" @default.
• W1983340908 startingPage "44" @default.
• W1983340908 abstract "► Two macro-acyclic ligands and their heterodinuclear complexes were prepared. ► The macrocyclic ligand contains a N 4 O 2 coordinate site and a N 2 O 2 coordination site. ► Geometrical isomerization occurs during the introduction of the second metal ion. ► The N–Zn–N bite angle in the N 4 O 2 site is responsible for the isomerization. Two phenol-based unsymmetrical dinucleating macro-acyclic ligands (LH 2 ), which can contiguously accommodate two metal ions, one in a hexa-coordinate (N 4 O 2 ) site and the other in a tetra-coordinate (N 2 O 2 ) site, and their heterodinuclear complexes [ZnLM II ] 2+ , where M = Cu or Ni, were prepared using a stepwise method. One of the ligand systems (L 3 H 2 ) comprises an ethylenediamine link in the N 4 O 2 compartment, whereas the other (L 6 H 2 ) includes an 1,3-diaminopropane link. Both ligands contain two methyl arms attached to the nitrogen atoms in the N 2 O 2 coordination site. The mononuclear complex of the type [ZnL 3 (H + ) 2 ] 2+ has a C 2 -symmetrical structure. When a second metal is incorporated, however, the resultant heterodinuclear complexes [ZnL 3 M II ] 2+ provide a non-symmetrical structure due to the occurrence of geometrical isomerization. In contrast, the mononuclear complex of the type [ZnL 6 (H + ) 2 ] 2+ demonstrated a mixture of topological isomers and the structures of the resultant heterodinuclear complexes [ZnL 6 M II ] 2+ , remained constant without a change in the structures with respect to the mononuclear complex. The origins of the structural variations are discussed. The structures of the complexes were studied by NMR, IR, UV–Vis spectroscopies and X-ray crystallography." @default.
• W1983340908 created "2016-06-24" @default.
• W1983340908 creator A5013759035 @default.
• W1983340908 creator A5016858866 @default.
• W1983340908 creator A5054938329 @default.
• W1983340908 creator A5078505093 @default.
• W1983340908 date "2012-08-01" @default.
• W1983340908 modified "2023-10-18" @default.
• W1983340908 title "Controlled syntheses of heterodinuclear complexes of a dicompartmental macro-acyclic ligand with hexa and tetra coordination sites" @default.
• W1983340908 cites W1967631572 @default.
• W1983340908 cites W1974121713 @default.
• W1983340908 cites W1975217371 @default.
• W1983340908 cites W1979063075 @default.
• W1983340908 cites W1980590245 @default.
• W1983340908 cites W1982886773 @default.
• W1983340908 cites W1993269903 @default.
• W1983340908 cites W1993823993 @default.
• W1983340908 cites W1998722626 @default.
• W1983340908 cites W2022532142 @default.
• W1983340908 cites W2028259143 @default.
• W1983340908 cites W2041212160 @default.
• W1983340908 cites W2041837068 @default.
• W1983340908 cites W2042386173 @default.
• W1983340908 cites W2045588645 @default.
• W1983340908 cites W2054224446 @default.
• W1983340908 cites W2065443350 @default.
• W1983340908 cites W2071063882 @default.
• W1983340908 cites W2071758004 @default.
• W1983340908 cites W2076872835 @default.
• W1983340908 cites W2083961493 @default.
• W1983340908 cites W2083982848 @default.
• W1983340908 cites W2094522816 @default.
• W1983340908 cites W2172115650 @default.
• W1983340908 doi "https://doi.org/10.1016/j.poly.2012.06.046" @default.
• W1983340908 hasPublicationYear "2012" @default.
• W1983340908 type Work @default.
• W1983340908 sameAs 1983340908 @default.
• W1983340908 citedByCount "1" @default.
• W1983340908 countsByYear W19833409082015 @default.
• W1983340908 crossrefType "journal-article" @default.
• W1983340908 hasAuthorship W1983340908A5013759035 @default.
• W1983340908 hasAuthorship W1983340908A5016858866 @default.
• W1983340908 hasAuthorship W1983340908A5054938329 @default.
• W1983340908 hasAuthorship W1983340908A5078505093 @default.
• W1983340908 hasConcept C11111787 @default.
• W1983340908 hasConcept C112887158 @default.
• W1983340908 hasConcept C115624301 @default.
• W1983340908 hasConcept C116569031 @default.
• W1983340908 hasConcept C126661725 @default.
• W1983340908 hasConcept C155647269 @default.
• W1983340908 hasConcept C161790260 @default.
• W1983340908 hasConcept C170493617 @default.
• W1983340908 hasConcept C178790620 @default.
• W1983340908 hasConcept C185592680 @default.
• W1983340908 hasConcept C194196696 @default.
• W1983340908 hasConcept C2777873363 @default.
• W1983340908 hasConcept C32909587 @default.
• W1983340908 hasConcept C544153396 @default.
• W1983340908 hasConcept C55493867 @default.
• W1983340908 hasConcept C68913812 @default.
• W1983340908 hasConcept C71240020 @default.
• W1983340908 hasConcept C8010536 @default.
• W1983340908 hasConcept C97343561 @default.
• W1983340908 hasConceptScore W1983340908C11111787 @default.
• W1983340908 hasConceptScore W1983340908C112887158 @default.
• W1983340908 hasConceptScore W1983340908C115624301 @default.
• W1983340908 hasConceptScore W1983340908C116569031 @default.
• W1983340908 hasConceptScore W1983340908C126661725 @default.
• W1983340908 hasConceptScore W1983340908C155647269 @default.
• W1983340908 hasConceptScore W1983340908C161790260 @default.
• W1983340908 hasConceptScore W1983340908C170493617 @default.
• W1983340908 hasConceptScore W1983340908C178790620 @default.
• W1983340908 hasConceptScore W1983340908C185592680 @default.
• W1983340908 hasConceptScore W1983340908C194196696 @default.
• W1983340908 hasConceptScore W1983340908C2777873363 @default.
• W1983340908 hasConceptScore W1983340908C32909587 @default.
• W1983340908 hasConceptScore W1983340908C544153396 @default.
• W1983340908 hasConceptScore W1983340908C55493867 @default.
• W1983340908 hasConceptScore W1983340908C68913812 @default.
• W1983340908 hasConceptScore W1983340908C71240020 @default.
• W1983340908 hasConceptScore W1983340908C8010536 @default.
• W1983340908 hasConceptScore W1983340908C97343561 @default.
• W1983340908 hasIssue "1" @default.
• W1983340908 hasLocation W19833409081 @default.
• W1983340908 hasOpenAccess W1983340908 @default.
• W1983340908 hasPrimaryLocation W19833409081 @default.
• W1983340908 hasRelatedWork W1414183263 @default.
• W1983340908 hasRelatedWork W2023423052 @default.
• W1983340908 hasRelatedWork W2039854732 @default.
• W1983340908 hasRelatedWork W2073749445 @default.
• W1983340908 hasRelatedWork W2083961493 @default.
• W1983340908 hasRelatedWork W2325311818 @default.
• W1983340908 hasRelatedWork W2332841977 @default.
• W1983340908 hasRelatedWork W2386046626 @default.
• W1983340908 hasRelatedWork W2995732731 @default.
• W1983340908 hasRelatedWork W3037272686 @default.
• W1983340908 hasVolume "44" @default.
• W1983340908 isParatext "false" @default.

• next