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- W1983350470 abstract "Abstract When guanosine (G) and cytidine (C) are present in dimethyl sulfoxide (DMSO), and in the mixed solvents DMSO-CCl 4 and DMSO-acetonitrile, a hydrogenbonded complex results. The equilibrium constant for complex formation at 32° is 4.0 ±0.4 in DMSO, and increases with decreasing concentration of DMSO in the mixed solvents. Acetonitrile is less “inert” than CCl 4 and the values of K in DMSO-CH 3 CN mixtures are lower than the values in DMSO-CCl 4 mixtures, of corresponding DMSO concentration. For the DMSO-CCl 4 mixed solvent system, a plot of K vs the solvent composition, S, where S is defined as S = (moles of DMSO)/(moles of DMSO+moles of CCl 4 ) is almost linear. An extrapolation to zero S gives K = 38, and this may be taken to be a minimal value for the equilibrium constant of reaction [1], unperturbed from the medium effect of DMSO." @default.
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- W1983350470 date "1970-01-01" @default.
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- W1983350470 title "Nuclear magnetic resonance study of guanosine-cytidine pairing in mixed solvents" @default.
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- W1983350470 doi "https://doi.org/10.1016/0022-2364(70)90083-1" @default.
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