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- W1983381978 abstract "The second order mutual reaction between isopropyl radicals has been studied over the temperature range 301–424 K. Kinetic measurements of the overall termination rate, using a molecular modulation spectrometer, have been combined with product analysis studies to determine Arrhenius parameters for the recombination (kr) and disproportionation reactions. The values obtained: kr= 1.4 × 10–11[exp(–1340 J mol–1//RT)] cm3 molecule–1 s–1, kd= 5.0 × 10–12[exp(210 J mol–1//RT)] cm3 molecule–1 s–1, give good agreement with product analysis studies over a wide range of temperatures. These rate coefficients are correct to ± 20% over the stated temperature range, and the error in the activation energies is ± 2600 J mol–1(95% confidence limits). The parameters for kr extrapolate to a value that is about twice the value measured by the very low pressure pyrolysis method at 750 K." @default.
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- W1983381978 date "1978-01-01" @default.
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- W1983381978 title "Mutual reaction of isopropyl radicals" @default.
- W1983381978 doi "https://doi.org/10.1039/f19787403016" @default.
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