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- W1983405908 abstract "The periselectivity of the photo-pericyclic reaction of cycloheptatriene(s) has been explained in terms of the charge capacity of the reaction-determining terminal radical carbon and the generalized valence bond orbital interactions (GVB-OIs), in general. The reaction-determining terminal radical carbon having a lower or higher value of charge capacity has been found to have a greater tendency for photo-sigmatropic migration or photo-electrocyclization respectively. A rational explanation for the dependence of the photo-pericyclic reaction of cycloheptatriene(s) on the wavelength of the irradiated light has been furnished." @default.
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- W1983405908 date "1997-10-01" @default.
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- W1983405908 title "An interpretative study on the photo-periselectivity of cycloheptatrienes and their wavelength dependence: Effect of charge capacity and GVB-OIs" @default.
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- W1983405908 doi "https://doi.org/10.1016/s0166-1280(96)04916-0" @default.
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