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• W1983453070 abstract "PVC membrane electrodes for lead ion based on meso-tetrakis(2-hydroxy-1-naphthyl)porphyrin (THNP: I) and meso-tetrakis(2-methoxy-1-naphthyl)porphyrin (TMNP: II) atropisomers as membrane carriers were prepared. Among their atropisomers, a membrane electrode (m-3) containing (α,α,α,α)-THNP (ID) as an ionophore and 2-nitrophenyl octyl ether (o-NPOE) as a plasticizer displays a good Nernstian response (29.2±0.3 mV/decade) to Pb2+ in Pb(NO3)2 solutions over the linear range of 3.2×10−5 to 1×10−1 M at room temperature. The limit of detection was 3.5×10−6 M. It has a fast response time within 10 s over the entire concentration range and the potentials remain constant for more than 5 min and can be used for at least 3 months without any divergence in potentials. The proposed electrode revealed good selectivity and response for Pb2+ over a wide variety of other metal ions in a pH 6.0 buffer solutions and good reproducibility of base line in subsequent measurements." @default.
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• W1983453070 date "2004-05-01" @default.
• W1983453070 modified "2023-10-04" @default.
• W1983453070 title "Lead(II)-selective electrodes based on tetrakis(2-hydroxy-1-naphthyl)porphyrins: the effect of atropisomers" @default.
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• W1983453070 doi "https://doi.org/10.1016/j.snb.2003.11.029" @default.
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