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- W1983472794 abstract "The title reactions have been studied to scrutinize rate data recently inferred for the two reverse steps – reaction of phenoxy radicals with chlorobenzene and bromobenzene – which were at variance with commonly accepted model values. Both with chlorine and bromine atoms, splitting to halobenzene and phenoxy radical was found to occur in competition with abstraction of o-, m-, p-hydrogen atoms. On this basis, the displacements of Cl and Br from the benzene ring by phenoxy radicals must have activation energies above 20 kcal/mol, and are therefore slow. As a consequence, formation of “dioxins” from halogenated phenols, in (slow) combustion, should proceed by combination of two (halo)phenoxy radicals rather than by displacement of (ortho-)halogen in a halophenol molecule." @default.
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- W1983472794 date "1999-01-01" @default.
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- W1983472794 title "Reactions of Diphenyl Ether with Chlorine and Bromine Atoms Around 750 K – Relevance for Gas-Phase “Dioxin” Formation" @default.
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- W1983472794 doi "https://doi.org/10.1002/(sici)1099-0690(199901)1999:1<261::aid-ejoc261>3.0.co;2-i" @default.
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