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- W1983485228 abstract "Shifts of the binding energies of x-ray-photoelectron core levels are observed in the ${mathrm{Bi}}_{2}$${mathrm{Sr}}_{2}$${mathrm{Ca}}_{1mathrm{ensuremath{-}}mathit{x}}$${mathrm{Y}}_{mathit{x}}$${mathrm{Cu}}_{2}$${mathrm{O}}_{mathit{y}}$ system when x is varied. It is pointed out that this is due to the change in the chemical environment associated with the changes of the interatomic distances. We show that the so-called bond-valence-sum calculation is useful for the explanation of the shift; and propose that this method is generally applicable in explaining or predicting the shift of core levels in any system with a variable composition." @default.
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- W1983485228 date "1991-03-01" @default.
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- W1983485228 title "Shift of x-ray-photoelectron core levels inBi2Sr2Ca1−xYxCu2Oy: An explanation by bond-valence-sum calculation" @default.
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- W1983485228 doi "https://doi.org/10.1103/physrevb.43.6249" @default.
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