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- W1983500676 abstract "The coordination chemistry of porphyrins towards the complexation of bimuth(III) has been investigated. Although the insertion of bismuth is tedious in porphyrins such as octa-ethyl porphyrin (OEP) or tetra-tolyl porphyrin (TTP), we have demonstrated that simple modifications of the ligand, like the grafting of arms bearing either ester groups or acid functions, lead to stable complexes, resulting from a rapid complexation reaction. La coordination du bismuth(III) par les porphyrines a été étudiée. Bien que l'insertion du bismuth soit réalisée difficilement dans des porphyrines telles que l'octa-éthylporphyrine (OEP) ou la meso-tétra-tolylporphyrine (TTP), nous avons pu montrer que de simples modifications du ligand, telles que le greffage d'un bras portant des fonctions ester ou acides, conduit à des complexes stables, résultant d'une réaction de complexation rapide." @default.
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- W1983500676 date "2007-07-01" @default.
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- W1983500676 title "The coordination of bismuth by porphyrins" @default.
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- W1983500676 doi "https://doi.org/10.1016/j.crci.2006.09.016" @default.
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