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- W1983507130 abstract "The chromium(0)-carbene complex benzannulation reaction was shown to be applicable to cyclodec-4-yn-1-one. Significant regioselectivity was realized in this reaction with ortho-substituted benzylchromium complexes. Reactions of a novel resultant fused cyclodecenone-naphthoquinone with several bases have been studied. Products apparently arising from either intramolecular Michael addition of a ketone enolate to the quinone or intramolecular aldol condensation of a quinone-stabilized anion with the ketone have been observed. The latter mode constitutes a route to the title substructure and, in principle, a route to reach certain angucycline antibiotics" @default.
- W1983507130 created "2016-06-24" @default.
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- W1983507130 date "2010-08-20" @default.
- W1983507130 modified "2023-09-26" @default.
- W1983507130 title "ChemInform Abstract: Studies in the Benzannulation of a Cycloalkynone: An Approach to the Synthesis of Antibiotics Containing the Benz(a)anthracene Core Structure." @default.
- W1983507130 cites W2949239525 @default.
- W1983507130 doi "https://doi.org/10.1002/chin.199320081" @default.
- W1983507130 hasPublicationYear "2010" @default.
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