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- W1983592073 abstract "Die Reaktion von Me4EI (EP, As), Me3EtSbI, Me2Et2SbI, MeEt3SbI oder Et4SbI mit I2 im Substanzgemisch ohne Lösungsmittel führt zu den entsprechenden Triiodiden Me4EI3 (EP, As), Me3EtSbI3, Me2Et2SbI3, MeEt3SbI3 oder Et4SbI3. Me4SbI3 entsteht in reversibler Reaktion durch Zugabe von I2 zu (Me4Sb)3I8 oder durch Umsetzung einer ethanolischen Lösung von Me4SbI mit einer Lösung von Iod in Benzol. Über die Kristallstrukturen von Me4EI3 (EP, Sb) und Me3EtSbI3 und die Synthese der neuen Verbindungen wird berichtet. Syntheses and Crystal Structure Analyses of Tetraalkyl Phosphonium, Arsonium, and Stibonium Triiodides The reaction of Me4EI (EP, As), Me3EtSbI, Me2Et2SbI, MeEt3SbI, or Et4SbI with I2 in absence of solvent gives Me4PI3 (EP, As), Me3EtSbI3, Me2Et2SbI3, MeEt3SbI3, or Et4SbI3. Me4SbI3 is formed in a reversible reaction by addition of I2 to (Me4Sb)3I8 or by reaction of a solution of Me4SbI in ethanol with I2 in benzene. The crystal structures of Me4EI3 (EP, Sb), and Me3EtSbI3 and the syntheses of the novel compounds are reported." @default.
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- W1983592073 date "1997-07-01" @default.
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- W1983592073 title "Synthesen und Kristallstrukturanalysen von Tetraalkylphosphonium-, -arsonium- und -stiboniumtriiodiden" @default.
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- W1983592073 doi "https://doi.org/10.1002/zaac.19976230724" @default.
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