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• W1983630859 abstract "Abstract Enantiomerically pure thiahelicenes displaying a terminal phosphole unit and a stereogenic phosphorus center have been prepared by oxidative photocyclization of a diaryl‐olefin precursor. Starting from one of these phosphathiahelicene oxides, the corresponding trivalent phosphine–Au I complex is obtained with complete diastereoselectivity. It affords a new, excellent precatalyst for the enantioselective cycloisomerization of N‐tethered enynes (up to 96 % ee )." @default.
• W1983630859 created "2016-06-24" @default.
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• W1983630859 date "2014-08-11" @default.
• W1983630859 modified "2023-10-18" @default.
• W1983630859 title "Phosphathiahelicenes: Synthesis and Uses in Enantioselective Gold Catalysis" @default.
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• W1983630859 doi "https://doi.org/10.1002/chem.201402822" @default.
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• W1983630859 hasPublicationYear "2014" @default.
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