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- W1983643246 abstract "A systematic study of the vacuum u.v. spectroscopy of ICN, BrCN and ClCN has been conducted based on measurements of the absorption spectrum, the photofragment excitation specrum of CN(B2Σ+), its relative quantum yield and the polarization of the CN(B→X) fluorescence emission as a function of wavelength in the range 120–180 nm. The results establish (1) that the B and C states are associated with perpendicular transisions into the 3II, (, ½)1 and 1II, (½, ½)1 components of the Rydberg states 2π→nsσ; (2) the important contributions made by an underlying continuum associated with a linear O+ or bent A′ upper state; (3) the presence of an intravalence transition in ClCN analogous to the ([graphic omitted]1A′â†� [graphic omitted]) band system in HCN, which was previously unrecognised; (4) the assignment of a number of Rydberg states associated with the 2II, 2II½ and 2Π½ states of the ionic core and (5) the influence of (Ωc, ω) coupling in complicating the spectroscopy of the heaviest of the cyanogen halides, ICN." @default.
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- W1983643246 date "1979-01-01" @default.
- W1983643246 modified "2023-09-26" @default.
- W1983643246 title "Photodissociation spectroscopy of the cyanogen halides in the vacuum ultraviolet" @default.
- W1983643246 doi "https://doi.org/10.1039/f29797501572" @default.
- W1983643246 hasPublicationYear "1979" @default.
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