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• W1983664253 abstract "A total of 608 pure rotational transitions for 1,1,2,2,3-pentafluorocyclobutane have been recorded and analyzed for the first time. Data analysis shows a dihedral angle for C4H3F5 which is intermediate between those of C4H8 and C4F8. The strong free induction decay (FID) collected has allowed for a singular value decomposition (SVD) signal processing method to be further examined in time domain rotational spectroscopy. Hankel matrices formed from the first 15 000 data points of the FID are capable of reproducing the parent molecules transition frequencies to an accuracy approaching that of the fast Fourier transformation. In addition to the FFT method the SVD method more readily produces information on transition phase, amplitude, and signal damping but at a significantly increased computational cost." @default.
• W1983664253 created "2016-06-24" @default.
• W1983664253 creator A5004472184 @default.
• W1983664253 creator A5055535795 @default.
• W1983664253 date "2014-12-01" @default.
• W1983664253 modified "2023-10-14" @default.
• W1983664253 title "The pure rotational spectrum of 1,1,2,2,3-pentafluorocyclobutane and applications of singular value decomposition signal processing" @default.
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• W1983664253 doi "https://doi.org/10.1016/j.jms.2014.10.007" @default.
• W1983664253 hasPublicationYear "2014" @default.
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