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- W1983668595 abstract "Sharp absorption lines produced by hydrogen in diamond have been studied in diamonds grown from 13C by high-pressure, high-temperature synthesis. Analyses of the two-phonon intrinsic absorption and of the Raman shift have shown that the 12C content of the diamond is 13.5%. This value is entirely consistent with the relative intensities of the absorption lines at 3107 and 3098 cm−1, confirming that they are due to a strongly localized C–H stretching vibration. A correlated line, observed at 1405 cm−1 for natural diamond, and attributed to the C–H bending vibration, exhibits both an isotope shift and a shift due to weak coupling with the one-phonon modes. By analogy with natural diamond, lines for the 13C diamond at 2757 and 4469 cm−1 are assigned to the combinations 2ωb and ωs + ωb, respectively, where ωs and ωb are the stretch and bend frequencies. The frequency invariance, on carbon isotope substitution, of a hydrogen-related line at 3237 cm−1 is not inconsistent with the proposal that this is produced by a N–H vibration." @default.
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- W1983668595 date "2003-05-07" @default.
- W1983668595 modified "2023-09-27" @default.
- W1983668595 title "Absorption spectra of hydrogen in<sup>13</sup>C diamond produced by high-pressure, high-temperature synthesis" @default.
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- W1983668595 doi "https://doi.org/10.1088/0953-8984/15/19/316" @default.
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