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- W1983669484 abstract "13 alkyl- and silylethylenes have been synthesized to determine their vertical ionization energies, characteristic IR frequencies, 1H NMR signals, π → π* electronic transitions, halfwave reduction potentials and ESR spin densities of their radical anions. The result confirm d/π interactions in the ground state and d/π interactions in the excited state of silylethylene-π-electron systems. The inductive polarization +I(SiR3) > +I(CR3) could be evaluated from the substituent effect of the R3SiCH2 group. 13 Alkyl- und Silyläthylene wurden gezielt synthetisiert, um ihre vertikalen Ionisierungsenergien, charakteristischen IR-Frequenzen, 1H-NMR-Signale, π → π*-Elektronenübergänge, Halbstufen-Reduktionspotentiale und ESR-Spindichten ihrer Radikalanionen zu bestimmen. Die Meßergebnisse belegen d/π-Wechselwirkungen im Grundzustand und d/π*-Wechselwirkungen im angeregten Zustand der Silyläthylen-π-Elektronensysteme. Die induktive Polarisation +I(SiR3) > +I(CR3) ließ sich aus dem Substituenteneffekt der R3SiCH2-Gruppen abschätzen." @default.
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- W1983669484 date "1968-07-01" @default.
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- W1983669484 title "d-orbitaleffekte in silizium-substituierten π-elektronensystemen VI. Spektroskopische untersuchungen an alkyl- und silyläthylenen" @default.
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- W1983669484 doi "https://doi.org/10.1016/s0022-328x(00)88859-2" @default.
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