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• W1983749474 abstract "The dichroic behaviour of 615 and 637 cm -1 bands of the IR spectrum of poly(vinyl chloride) (PVC) has been analysed through FTIR measurements on PVC films stretched to various elongation ratios. By comparing the evolution both of the dichroic ratios and of the relative absorbance of those bands in the perpendicular direction to that of stretching, the occurrence of local chain orientation related to the conformational change GTTG - TT ⇒ GTGTTT at mmr isotactic tetrads can be differentiated from the normal orientation of syndiotactic sequences, so confirming earlier proposals that the above conformational change takes place when stretching PVC." @default.
• W1983749474 created "2016-06-24" @default.
• W1983749474 creator A5031495471 @default.
• W1983749474 creator A5058143457 @default.
• W1983749474 date "1999-11-01" @default.
• W1983749474 modified "2023-10-17" @default.
• W1983749474 title "Irreversibility of stretching-induced local conformational changes as verified through an FTIR dichroism study for PVC" @default.
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• W1983749474 doi "https://doi.org/10.1002/(sici)1097-0126(199911)48:11<1108::aid-pi276>3.0.co;2-0" @default.
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