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- W1983775355 abstract "Lead dicyanamide, Pb[N(CN)2]2, was synthesized through ion exchange in water starting from Na[N(CN)2]. The crystal structure was determined by single-crystal X-ray diffraction (Pnma, Z=4, a=1350.45(10), b=399.89(4), c=1199.39(11) pm, R1=0.0275, wR2=0.0557, 68 parameters, 1073 independent reflections). In the solid Pb[N(CN)2]2 consists of Pb2+ ions and bent planar [N(CN)2]− ions. The dicyanamide anions exhibit CN bond lengths of 114.0(13)–116.0(10) pm to the terminal and 128.8(11)–131.9(12) pm to the bridging N atoms. The bond angles within the [N(CN)2]− ions are 173.1(8)–174.5(10)° (NCN) and 122.0(8)° (CNC). The crystal structure of Pb[N(CN)2]2 is isotypic with that of Ba[N(CN)2]2. It can be derived from the cotunnite structure type (PbCl2). Above 230 °C Pb[N(CN)2]2 transforms into amorphous products. Detailed IR spectroscopic data of Pb[N(CN)2]2 are reported. The observed frequencies agree well with those observed for isotypic Ba[N(CN)2]2." @default.
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- W1983775355 date "2002-05-01" @default.
- W1983775355 modified "2023-10-16" @default.
- W1983775355 title "Synthesis, crystal structure, vibrational spectroscopy, and thermal behaviour of lead dicyanamide Pb[N(CN)2]2" @default.
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- W1983775355 doi "https://doi.org/10.1016/s1293-2558(02)01325-0" @default.
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