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• W1983776631 endingPage "1898" @default.
• W1983776631 startingPage "1893" @default.
• W1983776631 abstract "New types of P,N-ligands, cis- and trans-3, containing a tetrahydroisoquinoline skeleton as an N-donor were synthesized from (1R,2S)-1-phenylphospholane-2-carboxylic acid (phenyl-P-proline, 1). The cis isomer, cis-3, was found to act as an excellent ligand in palladium-catalyzed asymmetric allylic substitution reactions. The reactions of 1,3-diphenyl-2-propenyl acetate (5) with several nucleophiles in the presence of [Pd(π-allyl)Cl]2, cis-3 (Pd : ligand=1 : 2), and a base afforded the desired products in high yields with high enantioselectivity. It was suggested that these ligands did not serve as P,N-bidentate ligands but as P-monodentate ligands in these reactions." @default.
• W1983776631 created "2016-06-24" @default.
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• W1983776631 date "2005-12-01" @default.
• W1983776631 modified "2023-10-16" @default.
• W1983776631 title "A New Chiral P,N-Ligand Derived from 1-Phenylphospholane-2-carboxylic Acid (Phenyl-P-proline) for Palladium-Catalyzed Asymmetric Allylic Substitution Reactions" @default.
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• W1983776631 doi "https://doi.org/10.1002/adsc.200505234" @default.
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