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- W1983780147 abstract "The self-assembled formation of a one-dimensional lanthanum salicylaldimine coordination polymer was proved by the X-ray diffraction analysis of new lanthanum(III) nitrate complex containing N,N'-bis(salicylidene)-1,5-pentanediamine ligand (H2L). It was obtained in situ in a one-step, metal-templated condensation of salicylaldehyde with 1,5-pentanediamine (cadaverine, biogenic polyamine) and characterized by microanalysis and spectroscopic (IR, ESI-MS, UV-Vis, and 1H NMR) data. The [La(NO3)3(μ-H2L)2]∞ complex displayed 10-coordinate distorted bicapped dodecahedron geometry with unusual coordination pattern of undeprotonated salicylaldimines which acted as μ-bridging ditopic ligands using exclusively the oxygens as donor atoms with the nitrogen atoms not being involved in the coordination environment." @default.
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- W1983780147 date "2010-12-01" @default.
- W1983780147 modified "2023-09-24" @default.
- W1983780147 title "Self-assembly as a route to one-dimensional lanthanum(III) salicylaldimine coordination polymer" @default.
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- W1983780147 doi "https://doi.org/10.1016/s1002-0721(10)60387-0" @default.
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