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- W1983795015 abstract "The hydrogen electrode reaction involving hydride ion, H-, at a Zn electrode is investigated in a molten LiCl−KCl−LiH system at 673 K. The charge-transfer resistances were measured by electrochemical impedance spectroscopy in the overpotential region of 0.10 ≤ η ≤ 0.35 V and over the H- concentrations of 1.5 × 10-4 ≤ CH- ≤ 1.2 × 10-3 mol cm-3. The logarithm plot of the charge-transfer resistance against the overpotential at CH- = 3.0 × 10-4 mol cm-3 gives the symmetry factor, β, of 0.50 and the exchange current density, j0, of 5.8 × 10-3A cm-2, respectively. Analysis of the dependence of j0 on H- concentration independently gives a β of 0.55. The reasonable β values indicate that the H- ⇌ Had(M) + e- step is rate-determining." @default.
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- W1983795015 date "2005-05-01" @default.
- W1983795015 modified "2023-10-18" @default.
- W1983795015 title "Electrochemical Impedance Spectroscopy Study of a Hydrogen Electrode Reaction at a Zn Electrode in a Molten LiCl−KCl−LiH System" @default.
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- W1983795015 doi "https://doi.org/10.1021/jp044477z" @default.
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