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• W1983807712 endingPage "3586" @default.
• W1983807712 startingPage "3575" @default.
• W1983807712 abstract "The use of salicylaldehyde oxime (H2salox) in manganese(III) carboxylate chemistry has yielded new members of the family of hexanuclear compounds presenting the [Mn6(μ3-O)2(μ2-OR)2]12+ core, complexes [MnIII6(μ3-O)2(O2CPh)2(salox)6(L1)2(L2)2] (L1 = py, L2 = H2O (1); L1 = Me2CO, L2 = H2O (2); L1 = L2 = MeOH (3)). Addition of NaOMe to the acetonitrile reaction mixture, afforded the 1D complex [MnIII3Na(μ3-O)(O2CPh)2(salox)3(MeCN)]n (4), whereas addition of NaClO4 to the acetone reaction mixture afforded an analogous 1D complex [MnIII3Na(μ3-O)(O2CPh)2(salox)3(Me2CO)]n (5). The structures of 1–3 present the [Mn6(μ3-O)2(μ2-OR)2]12+ core and can be described as two [Mn3(μ3-O)]7+ triangular subunits linked by two μ2-oximato oxygen atoms of the salox2− ligands, which show the less common μ3-κ2O:κO′:κN coordination mode. The benzoato ligands are coordinated through the usual syn,syn-μ2-κO:κO′ mode. The 1D polymeric structures of 4 and 5 consist of alternating [Mn3(μ3-O)]7+ subunits and Na+ atoms linked through two μ3-κ2O:κO′:κN and one μ4-κ2O:κ2O′:κN salox2− ligands as well as one syn,anti-μ2-κO:κO′ benzoato ligand. DC and AC magnetic susceptibility studies on 1 revealed the stabilization of an S = 4 ground state, and indications of single-molecule magnetism behavior, whereas the DC experimental data from polycrystalline sample of 5 are indicative of antiferromagnetic interactions within the [Mn3] subunit. Solid state 1H NMR data of 1 were used to probe the spin-lattice relaxation of the system." @default.
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• W1983807712 date "2008-12-01" @default.
• W1983807712 modified "2023-10-18" @default.
• W1983807712 title "Salicylaldoxime in manganese(III) carboxylate chemistry: Synthesis, structural characterization and physical studies of hexanuclear and polymeric complexes" @default.
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• W1983807712 cites W1525620422 @default.
• W1983807712 cites W1964200474 @default.
• W1983807712 cites W1965022350 @default.
• W1983807712 cites W1965284073 @default.
• W1983807712 cites W1970432994 @default.
• W1983807712 cites W1970759507 @default.
• W1983807712 cites W1973629325 @default.
• W1983807712 cites W1973934105 @default.
• W1983807712 cites W1979247652 @default.
• W1983807712 cites W1979956099 @default.
• W1983807712 cites W1983300609 @default.
• W1983807712 cites W1990654323 @default.
• W1983807712 cites W1993784539 @default.
• W1983807712 cites W2003309734 @default.
• W1983807712 cites W2008141942 @default.
• W1983807712 cites W2008365946 @default.
• W1983807712 cites W2010731973 @default.
• W1983807712 cites W2011868699 @default.
• W1983807712 cites W2016224635 @default.
• W1983807712 cites W2023759119 @default.
• W1983807712 cites W2024494256 @default.
• W1983807712 cites W2026722373 @default.
• W1983807712 cites W2029810834 @default.
• W1983807712 cites W2031204731 @default.
• W1983807712 cites W2032556254 @default.
• W1983807712 cites W2034644474 @default.
• W1983807712 cites W2035799110 @default.
• W1983807712 cites W2051091256 @default.
• W1983807712 cites W2051478709 @default.
• W1983807712 cites W2052505288 @default.
• W1983807712 cites W2054314491 @default.
• W1983807712 cites W2056449341 @default.
• W1983807712 cites W2058528394 @default.
• W1983807712 cites W2061439285 @default.
• W1983807712 cites W2063578222 @default.
• W1983807712 cites W2063695143 @default.
• W1983807712 cites W2066634884 @default.
• W1983807712 cites W2069210321 @default.
• W1983807712 cites W2071202770 @default.
• W1983807712 cites W2072046110 @default.
• W1983807712 cites W2074354806 @default.
• W1983807712 cites W2074900494 @default.
• W1983807712 cites W2075384751 @default.
• W1983807712 cites W2077974690 @default.
• W1983807712 cites W2079455656 @default.
• W1983807712 cites W2080614262 @default.
• W1983807712 cites W2083046671 @default.
• W1983807712 cites W2084573520 @default.
• W1983807712 cites W2085794105 @default.
• W1983807712 cites W2085819780 @default.
• W1983807712 cites W2086573906 @default.
• W1983807712 cites W2087041994 @default.
• W1983807712 cites W2087069137 @default.
• W1983807712 cites W2087404722 @default.
• W1983807712 cites W2089398889 @default.
• W1983807712 cites W2092308338 @default.
• W1983807712 cites W2092396024 @default.
• W1983807712 cites W2108374495 @default.
• W1983807712 cites W2119524324 @default.
• W1983807712 cites W2120968281 @default.
• W1983807712 cites W2121808696 @default.
• W1983807712 cites W2138772120 @default.
• W1983807712 cites W2146099614 @default.
• W1983807712 cites W2147482079 @default.
• W1983807712 cites W2153181096 @default.
• W1983807712 cites W2153267063 @default.
• W1983807712 cites W2155781916 @default.
• W1983807712 cites W2157986221 @default.
• W1983807712 cites W2162480985 @default.
• W1983807712 cites W2333655648 @default.
• W1983807712 cites W2335014206 @default.
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• W1983807712 doi "https://doi.org/10.1016/j.poly.2008.08.021" @default.
• W1983807712 hasPublicationYear "2008" @default.
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