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• W1983840003 abstract "Abstract We present 100 % selectivity to p‐ chloroaniline through the continuous gas‐phase (atmospheric pressure; T =393–523 K) catalytic hydrogenation of p‐ chloronitrobenzene over an activated CuAl (molar Cu/Al ratio 3:1) hydrotalcite. The synthesis by continuous co‐precipitation and application of a CuNiAl (atomic Cu/Ni/Al ratio 2.75:0.25:1) catalyst is also described. Temperature‐programmed reduction in hydrogen and XPS analyses of the ternary catalyst suggest CuNi interaction with no evidence of (bulk) alloy formation (based on XRD). Under the same reaction conditions, CuNiAl exhibited a higher (by up to a two‐fold) hydrogenation rate when compared to CuAl, while the exclusive nitro‐group reduction was maintained." @default.
• W1983840003 created "2016-06-24" @default.
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• W1983840003 date "2012-03-01" @default.
• W1983840003 modified "2023-10-18" @default.
• W1983840003 title "Promotional Effect of Ni in the Selective Gas-Phase Hydrogenation of Chloronitrobenzene over Cu-based Catalysts" @default.
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• W1983840003 doi "https://doi.org/10.1002/cctc.201100470" @default.
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