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- W1983861350 abstract "The new compound HoCo3P2 was prepared by reaction of the elemental components in a tin flux. Its crystal structure was determined from single-crystal X-ray data and refined to a residual of R = 0.055 for 2441 unique structure factors and 50 variable parameters. It is of a new orthorhombic type, space group Pmmn-D2h13 with Z = 6 formula units per cell, and the lattice constants a = 10.560(2) Å, b = 3.688(1) A, c = 12.233(2) A, V = 476.4 Å3. The structure may be viewed as built up by parallel corner-sharing phosphorus-centered metal prisms and thus can be considered as closely related to several other structures, all with a metal:metalloid ratio of 2:1, namely, the structures of Fe2P, Zr2Fe12P7, Hf2Co4P3, TiNiSi, YNi5Si3, YCo5P3, and LaCo5P3. These structures, however, show a considerable variety in the coordination polyhedra of the metal atoms. The compounds LnCo3P2 (Ln ≡ Tb, Dy, Er, Tm, Yb, Lu) are isotypic with HoCo3P2." @default.
- W1983861350 created "2016-06-24" @default.
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- W1983861350 date "1985-08-01" @default.
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- W1983861350 title "Preparation and crystal structure of the holmium cobalt phosphide HoCo3P2 and isotypic lanthanoid cobalt phosphides" @default.
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- W1983861350 doi "https://doi.org/10.1016/0022-5088(85)90342-x" @default.
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