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• W1983901896 abstract "Abstract Three new manganese(II) binuclear complexes, namely [Mn2(NPTA)(Phen)4](ClO4)2.2H2O (complex 1), [Mn2(NPTA)(Nphen)4]-(ClO4)2.4H2O(complex 2) and [Mn2(NPTA)(Bpy)4](ClO4)2 (complex 3) (NPTA = 4-nitrophthalate, Phen = 1,10-phenanthroline, Nphen = 5-nitro-1,10-phenanthroline, Bpy = 2,2′-bipyridyl), have been synthesized with 4-nitrophthalato as bridging ligand. The complexes were characterized by elemental analyses, IR, molar conductance, electronic reflection spectra and ESR spectra. These complexes are proposed to have extended 4-nitrophthalato-bridged structures and to consist of two manganese(II) atoms in a distorted octahedral environment. The temperature dependent magnetic susceptibility of complex 1 was measured over the temperature range 4.2–300 K. The magnetic coupling parameter is consistent with antiferromagnetic exchange between the two manganese(II) centers and fits the data of a binuclear magnetic exchange model based on the Hamiltonian operator (H =-2JS1S2), giving the antiferromagnetic..." @default.
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• W1983901896 date "1996-08-01" @default.
• W1983901896 modified "2023-09-24" @default.
• W1983901896 title "Syntheses and Magnetism of μ-4-Nitrophthalato Manganese(II) Binuclear Complexes" @default.
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• W1983901896 doi "https://doi.org/10.1080/00945719608004360" @default.
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