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• W1983912356 abstract "Hydrophobicity, the spontaneous segregation of oil and water, can be modified by surfactants. The way this modification occurs is studied at the oil–water interface for a range of alkanes and two ionic surfactants. A liquid interfacial monolayer, consisting of a mixture of alkane molecules and surfactant tails, is found. Upon cooling, it freezes at T s , well above the alkane’s bulk freezing temperature, T b . The monolayer’s phase diagram, derived by surface tensiometry, is accounted for by a mixtures-based theory. The monolayer’s structure is measured by high-energy X-ray reflectivity above and below T s . A solid–solid transition in the frozen monolayer, occurring approximately 3 °C below T s , is discovered and tentatively suggested to be a rotator-to-crystal transition." @default.
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• W1983912356 date "2011-03-21" @default.
• W1983912356 modified "2023-10-16" @default.
• W1983912356 title "Modification of deeply buried hydrophobic interfaces by ionic surfactants" @default.
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• W1983912356 doi "https://doi.org/10.1073/pnas.1014100108" @default.
• W1983912356 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3078380" @default.
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