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- W1983977633 abstract "The title compound, [CoCl(C12H8N2)2(H2O)]Cl·[CoCl2(C12H8N2)2]·6H2O, is the first example of a new 1:1 cocrystal of the octahedral [CoCl2(phen)2] and [CoCl(phen)2(H2O)]+·Cl− complexes (phen is 1,10-phenanthroline). The latter form heterochiral dimers held by strong π–π stacking interactions via their phenathroline ligands, which confirms that π stacking is an important and reliable synthon in supramolecular design. In addition, the crystal structure is networked by H2O⋯H2O, H2O⋯Cl− and H2O⋯Cl hydrogen bonds, which interconnect the different units of the cobalt complexes." @default.
- W1983977633 created "2016-06-24" @default.
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- W1983977633 date "2008-01-12" @default.
- W1983977633 modified "2023-09-27" @default.
- W1983977633 title "Hydrogen-bonding and π–π stacking interactions in aquachloridobis(1,10-phenanthroline)cobalt(II) chloride dichloridobis(1,10-phenanthroline)cobalt(II) hexahydrate" @default.
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- W1983977633 doi "https://doi.org/10.1107/s0108270107064803" @default.
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