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- W1984002015 abstract "The dynamics of vesicle formation following the rapid mixing of cationic and anionic surfactant solutions, and of their breakup, have been monitored using time-resolved light scattering. Two anionic/cationic surfactant pairs were used in these experimentssodium octyl sulfate (SOS)/cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate (SDS)/dodecyltrimethylammonium bromide (DTAB). The observed temporal variations in scattering intensities over a wide range of surfactant compositions are consistent with vesicle formation being a sequence of a fast process (complete within 4 ms, the ‘dead' time in our stopped-flow apparatus), followed by one or more processes which, when analyzed as a series of first-order events, yield apparent characteristic time constants of ∼10, ∼100, and ∼2000 s. Scattering intensities at 4 ms after mixing are two- to four-fold higher than those from either of the feeds, indicating that the first process consists of the formation of nonequilibrium mixed aggregates. Addition o..." @default.
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- W1984002015 date "1997-12-01" @default.
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- W1984002015 title "Dynamics of Micelle−Vesicle Transitions in Aqueous Anionic/Cationic Surfactant Mixtures" @default.
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- W1984002015 doi "https://doi.org/10.1021/la970491+" @default.
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