Matches in SemOpenAlex for { <https://semopenalex.org/work/W1984004807> ?p ?o ?g. }
- W1984004807 endingPage "5698" @default.
- W1984004807 startingPage "5691" @default.
- W1984004807 abstract "A non-Bornian theory has been proposed for the standard Gibbs free energy of ion transfer at the organic solvent (O)/water (W) interface. In this theory the ionic charge (z)-dependent term of , which has so far been considered as describing electrostatic (i.e., long-range) ion−solvent interactions, is treated as describing the specific (short-range) interactions. A quantum chemical consideration has shown that the short-range interaction energy can be given by a quadratic function of the surface field strength (E) of an ion. In the present theory it should also be noted that a hydrophilic ion, being preferentially hydrated in the O phase, is assumed to transfer across the interface as the hydrated ion. The new, non-Bornian theory has been applied to 34 ions in the nitrobenzene (NB)/W system. In the data analyses the ions have been classified into five groups, including hydrated cations, nonhydrated cations, hydrated anions, nonhydrated anions, and polyoxometalate anions (nonhydrated), where “hydrated” or “nonhydrated” means that the ion is associated with some water molecules in NB or not. Regression analyses have shown that in accord with the theory, the z-dependent term of can be given by a quadratic function of E for each group of ions. Furthermore, the present theory has been found to be useful for the prediction of for some hydrophilic ions." @default.
- W1984004807 created "2016-06-24" @default.
- W1984004807 creator A5069072292 @default.
- W1984004807 creator A5078285468 @default.
- W1984004807 date "1998-06-29" @default.
- W1984004807 modified "2023-10-18" @default.
- W1984004807 title "Non-Bornian Theory of the Gibbs Energy of Ion Transfer between Two Immiscible Liquids" @default.
- W1984004807 cites W1562583535 @default.
- W1984004807 cites W1583181657 @default.
- W1984004807 cites W1964357551 @default.
- W1984004807 cites W1970224412 @default.
- W1984004807 cites W1973581014 @default.
- W1984004807 cites W1976252757 @default.
- W1984004807 cites W1980427739 @default.
- W1984004807 cites W1982830242 @default.
- W1984004807 cites W1983130103 @default.
- W1984004807 cites W1984013971 @default.
- W1984004807 cites W1993327079 @default.
- W1984004807 cites W1995130462 @default.
- W1984004807 cites W2003930147 @default.
- W1984004807 cites W2012390987 @default.
- W1984004807 cites W2014595419 @default.
- W1984004807 cites W2021378877 @default.
- W1984004807 cites W2024003867 @default.
- W1984004807 cites W2025078519 @default.
- W1984004807 cites W2028667271 @default.
- W1984004807 cites W2029808388 @default.
- W1984004807 cites W2047266051 @default.
- W1984004807 cites W2050300179 @default.
- W1984004807 cites W2052022435 @default.
- W1984004807 cites W2052774587 @default.
- W1984004807 cites W2052876740 @default.
- W1984004807 cites W2054830971 @default.
- W1984004807 cites W2056582580 @default.
- W1984004807 cites W2060912158 @default.
- W1984004807 cites W2061490726 @default.
- W1984004807 cites W2064164620 @default.
- W1984004807 cites W2069975012 @default.
- W1984004807 cites W2070012613 @default.
- W1984004807 cites W2073328488 @default.
- W1984004807 cites W2079015357 @default.
- W1984004807 cites W2080685519 @default.
- W1984004807 cites W2085667494 @default.
- W1984004807 cites W2086988375 @default.
- W1984004807 cites W2087972921 @default.
- W1984004807 cites W2088910355 @default.
- W1984004807 cites W2126594858 @default.
- W1984004807 cites W2167590372 @default.
- W1984004807 cites W2169383619 @default.
- W1984004807 cites W2322814767 @default.
- W1984004807 cites W2323162670 @default.
- W1984004807 cites W2324824843 @default.
- W1984004807 cites W27727037 @default.
- W1984004807 doi "https://doi.org/10.1021/jp9814193" @default.
- W1984004807 hasPublicationYear "1998" @default.
- W1984004807 type Work @default.
- W1984004807 sameAs 1984004807 @default.
- W1984004807 citedByCount "90" @default.
- W1984004807 countsByYear W19840048072012 @default.
- W1984004807 countsByYear W19840048072013 @default.
- W1984004807 countsByYear W19840048072014 @default.
- W1984004807 countsByYear W19840048072015 @default.
- W1984004807 countsByYear W19840048072016 @default.
- W1984004807 countsByYear W19840048072017 @default.
- W1984004807 countsByYear W19840048072018 @default.
- W1984004807 countsByYear W19840048072019 @default.
- W1984004807 countsByYear W19840048072020 @default.
- W1984004807 countsByYear W19840048072021 @default.
- W1984004807 countsByYear W19840048072022 @default.
- W1984004807 countsByYear W19840048072023 @default.
- W1984004807 crossrefType "journal-article" @default.
- W1984004807 hasAuthorship W1984004807A5069072292 @default.
- W1984004807 hasAuthorship W1984004807A5078285468 @default.
- W1984004807 hasConcept C121332964 @default.
- W1984004807 hasConcept C145148216 @default.
- W1984004807 hasConcept C146477669 @default.
- W1984004807 hasConcept C147597530 @default.
- W1984004807 hasConcept C147789679 @default.
- W1984004807 hasConcept C152365726 @default.
- W1984004807 hasConcept C159467904 @default.
- W1984004807 hasConcept C159985019 @default.
- W1984004807 hasConcept C161790260 @default.
- W1984004807 hasConcept C178790620 @default.
- W1984004807 hasConcept C179104552 @default.
- W1984004807 hasConcept C185592680 @default.
- W1984004807 hasConcept C192562407 @default.
- W1984004807 hasConcept C204323151 @default.
- W1984004807 hasConcept C2182769 @default.
- W1984004807 hasConcept C2780471494 @default.
- W1984004807 hasConcept C2780809723 @default.
- W1984004807 hasConcept C32909587 @default.
- W1984004807 hasConcept C97355855 @default.
- W1984004807 hasConceptScore W1984004807C121332964 @default.
- W1984004807 hasConceptScore W1984004807C145148216 @default.
- W1984004807 hasConceptScore W1984004807C146477669 @default.
- W1984004807 hasConceptScore W1984004807C147597530 @default.
- W1984004807 hasConceptScore W1984004807C147789679 @default.
- W1984004807 hasConceptScore W1984004807C152365726 @default.