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- W1984006936 abstract "This work concerns the coordination chemistry of cadmium(II) tri-tert-butoxysilanethiolates in the presence of aliphatic diamines. Reactions of the binuclear [Cd{SSi(OtBu)3}2]2 with the respective diamines yielded five new neutral one-dimensional coordination polymers, [Cd{SSi(OtBu)3}2(μ-C4H12N2)(CH3OH)]n (1), [Cd{SSi(OtBu)3}2(μ-C5H14N2)(CH3OH)]n (2), [Cd{SSi(OtBu)3}2(μ-C6H16N2)(CH3OH)]n (3), [Cd{SSi(OtBu)3}2(μ-C7H18N2)]n (4) and [Cd{SSi(OtBu)3}2(μ-C8H20N2)]n (5), which adopt different spatial chain topologies. The new polymers were fully characterized by X-ray single-crystal diffraction, elemental analysis and IR spectroscopy. The thermal stabilities of complexes (1), (3) and (4) complexes were studied by thermogravimetry (TG, DTG)." @default.
- W1984006936 created "2016-06-24" @default.
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- W1984006936 date "2013-02-01" @default.
- W1984006936 modified "2023-10-18" @default.
- W1984006936 title "One dimensional coordination polymers generated from Cd(II) tri-tert-butoxysilanethiolates and flexible aliphatic diamines" @default.
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- W1984006936 doi "https://doi.org/10.1016/j.poly.2012.10.035" @default.
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