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- W1984085957 abstract "Abstract The 4‐imidazolecarboxylic acid ester of N,N ‐dihexadecyl‐ N ‐methyl‐ N ‐(β‐hydroxyethyl)ammonium chloride ( 1 ) and an analogous monohexadecyldi‐methylammonium ion surfactant ( 2 ) were prepared from readily available starting materials. Surfactant ( 1 ) formed fully‐functionalized imidazole vesicles which are powerful catalysts for the cleavage of p ‐nitrophenyl acetate, p ‐nitrophenyl hexanoate and 4‐acetoxy‐3‐nitrobenzenesulfonate. Maximum observed rate constants ([1] = 3.4 × 10 −3 M, pH 8.0, 0.01 Tris buffer, μ = 0.01, 25°C) are 2.82, 16.3 and 14.3 s −1 , respectively, for the three substrates. These and related kinetic parameters are compared with those of imidazole‐functionalized micellar surfactants, such as 2." @default.
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- W1984085957 date "1985-01-01" @default.
- W1984085957 modified "2023-10-14" @default.
- W1984085957 title "The Preparation and Kinetic Properties of Fully-Functionalized Imidazole Vesicles" @default.
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- W1984085957 doi "https://doi.org/10.1002/ijch.198500003" @default.
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