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• W1984129497 abstract "Nine bis-9,10-dihydrophenanthrene and 9,10-dihydrophenanthrene/(dihydro)stilbene derivatives, including the new phochinenins G-L 1–6, were isolated from the whole plant of Pholidota chinensis. Their structures were elucidated on the basis of extensive spectroscopic investigations (1D, 2D NMR, and HR-EIMS). Owing to the sterically hindered rotation around the biaryl axis, some of these biaryl compounds can exist as a pair of enantiomers, but were isolated as racemates. Computed inversion barriers of selected atropisomeric derivatives suggested that phochinenins K 5, gymconpin C 7, and flavanthrin 9 have stable atropisomers. Their racemates were separated by HPLC on an optically active stationary phase, and were stereochemically characterized on-line by circular dichroism (CD) spectroscopy (LC-CD coupling), in conjunction with quantum-mechanics CD calculations." @default.
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• W1984129497 date "2008-09-01" @default.
• W1984129497 modified "2023-09-30" @default.
• W1984129497 title "Stereochemistry of atropisomeric 9,10-dihydrophenanthrene dimers from Pholidota chinensis" @default.
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• W1984129497 doi "https://doi.org/10.1016/j.tetasy.2008.08.013" @default.
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