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- W1984172914 abstract "A family of ESR spectra from KClO3 crystals irradiated with x rays at 26 K are assigned to electron-excess defects consisting of O− ions trapped in different environments, which may be identified because the electron spin on O− polarizes the adjacent ions. In the primary configurations, O− is associated with ClO−2. Secondary configurations, in which O− is trapped between two ClO−3 ions, arise from a thermally activated substitution process of the Grotthuss type: leading to migration of the excess negative charge along the crystallographic axis a. The O− defects in KClO3 are structurally very similar to those observed earlier in irradiated KClO4. As in KClO4, O− reacts with O2 at ∼230 K to yield O−3." @default.
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- W1984172914 date "1981-09-15" @default.
- W1984172914 modified "2023-10-16" @default.
- W1984172914 title "O− detected by ESR as a radiation‐induced electron‐excess defect in KClO3" @default.
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- W1984172914 doi "https://doi.org/10.1063/1.442422" @default.
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